The effect of spin-orbit coupling on molecular properties: Potential energy curve, transition dipole moment and laser cooling scheme of NH.

The influence of spin-orbit coupling on the cooling of NH molecular laser is investigated based on the ab initio theory. The potential energy curves (PECs) and spectral constants for four Λ-S states (X3Σ-, a1Δ, b1Σ+ and A3Π) and eight Ω states [Formula: see text] a1Δ2, [Formula: see text] and [Formula: see text] ) of NH molecule are obtained by the multi-reference configuration interaction (MRCI) plus Davidson correction. The spectroscopic constants (Re, ωe, ωeχe, Be, De) are obtained by solving the one dimensional radial Schrödinger equation, and the results are almost the same as the previously reported data. In addition, the transition dipole moment, permanent dipole moment, Franck-Condon factors, and radiative lifetime of NH molecule are also acquired. Also, the effects of the intermediate state on the [Formula: see text] , [Formula: see text] and [Formula: see text] transitions are considered. The feasible laser cooling schemes using a single laser are formulated. In the proposed cooling scheme, there wavelengths for the [Formula: see text] are used, the main pump lasers are λ00 = 335.74 nm. The feasible transition is based on this. It is found that spin-orbit coupling has a significant effect on potential energy curves, permanent dipole moments, transition dipole moments and vibration energy levels.

Recent Progress on NIR-II Photothermal Therapy.

Photothermal therapy is a very promising treatment method in the field of cancer therapy. The photothermal nanomaterials in near-infrared region (NIR-I, 750-900 nm) attracts extensive attention in recent years because of the good biological penetration of NIR light. However, the penetration depth is still not enough for solid tumors due to high tissue scattering. The light in the second near-infrared region (NIR-II, 1000-1700 nm) allows deeper tissue penetration, higher upper limit of radiation and greater tissue tolerance than that in the NIR-I, and it shows greater application potential in photothermal conversion. This review summarizes the photothermal properties of Au nanomaterials, two-dimensional materials, metal oxide sulfides and polymers in the NIR-II and their application prospects in photothermal therapy. It will arouse the interest of scientists in the field of cancer treatment as well as nanomedicine.